The weakest bond: Collisions of helium dimers with xenon atoms

被引:6
作者
Buonomo, E [1 ]
Gianturco, FA [1 ]
Ragnetti, F [1 ]
机构
[1] UNIV ROME,DEPT CHEM,CITTA UNIV,I-00185 ROME,ITALY
关键词
D O I
10.1021/jp953386m
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The existence of an He-2 bound start is employed in an analysis of the possible outcomes from the low-energy collisions between helium dimers and xenon atoms that are currently being observed in molecular beam experiments. Existing interaction potentials between helium atoms and between He and Xe atoms ape used to construct the necessary potential energy surface (PE). Various dynamical approximations for the evaluation of elastic and total cross sections are reviewed, and the results are analyzed in detail, helping us to clarify the specific physical meanings of the various decoupling schemes used in the calculations. The special nature of this unusual diatomic target turns out to play, as expected, a crucial role in the cross section behavior at low collision energies.
引用
收藏
页码:9206 / 9215
页数:10
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