Efficient and reproducible CH3NH3PbI3-x(SCN)x perovskite based planar solar cells

被引：158

作者：

Chen, Yani ^{[1
]}

Li, Bobo ^{[2
,3
]}

Huang, Wei ^{[2
,3
]}

Gao, Deqing ^{[2
,3
]}

Liang, Ziqi ^{[1
]}

机构：

[1] Fudan Univ, Dept Mat Sci, Shanghai 200433, Peoples R China

[2] Nanjing Tech Univ NanjingTech, Jiangsu Natl Synergist Innovat Ctr Adv Mat SICAM, Key Lab Flexible Elect KLOFE, Nanjing 211816, Jiangsu, Peoples R China

[3] Nanjing Tech Univ NanjingTech, Jiangsu Natl Synergist Innovat Ctr Adv Mat SICAM, Inst Adv Mat, Nanjing 211816, Jiangsu, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 60期

基金：

中国国家自然科学基金;

关键词：

PERFORMANCE; PASSIVATION; HYSTERESIS; ABSORPTION; MORPHOLOGY; ABSORBER; FILMS;

D O I：

10.1039/c5cc03615a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report the addition of a small amount of Pb(SCN)(2) into PbI2 in a two-step solution method. The resulting CH3NH3PbI3-x(SCN)(x) perovskite films present larger-sized crystals and fewer traps than CH3NH3PbI3. Their planar solar cells exhibit a maximum power conversion efficiency of 11.07% with remarkably high reproducibility and good stability.

引用

页码：11997 / 11999

页数：3

共 30 条

[1] Synthesis and crystal chemistry of the hybrid perovskite (CH3NH3) PbI3 for solid-state sensitised solar cell applications [J].

Baikie, Tom ;

Fang, Yanan ;

Kadro, Jeannette M. ;

Schreyer, Martin ;

Wei, Fengxia ;

Mhaisalkar, Subodh G. ;

Graetzel, Michael ;

White, Tim J. .

JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (18) :5628-5641

[2] Efficient planar heterojunction mixed-halide perovskite solar cells deposited via spray-deposition [J].

Barrows, Alexander T. ;

Pearson, Andrew J. ;

Kwak, Chan Kyu ;

Dunbar, Alan D. F. ;

Buckley, Alastair R. ;

Lidzey, David G. .

ENERGY & ENVIRONMENTAL SCIENCE, 2014, 7 (09) :2944-2950

[3] Low-Temperature Fabrication of Efficient Wide-Bandgap Organolead Trihalide Perovskite Solar Cells [J].

Bi, Cheng ;

Yuan, Yongbo ;

Fang, Yanjun ;

Huang, Jinsong .

ADVANCED ENERGY MATERIALS, 2015, 5 (06)

[4] Controllable Self-Induced Passivation of Hybrid Lead Iodide Perovskites toward High Performance Solar Cells [J].

Chen, Qi ;

Zhou, Huanping ;

Song, Tze-Bin ;

Luo, Song ;

Hong, Ziruo ;

Duan, Hsin-Sheng ;

Dou, Letian ;

Liu, Yongsheng ;

Yang, Yang .

NANO LETTERS, 2014, 14 (07) :4158-4163

[5] Planar Heterojunction Perovskite Solar Cells via Vapor-Assisted Solution Process [J].

Chen, Qi ;

Zhou, Huanping ;

Hong, Ziruo ;

Luo, Song ;

Duan, Hsin-Sheng ;

Wang, Hsin-Hua ;

Liu, Yongsheng ;

Li, Gang ;

Yang, Yang .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (02) :622-625

[6] Nonvolatile chlorinated additives adversely influence CH3NH3PbI3 based planar solar cells [J].

Chen, Yani ;

Zhao, Yixin ;

Liang, Ziqi .

JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (17) :9137-9140

[7] Non-Thermal Annealing Fabrication of Efficient Planar Perovskite Solar Cells with Inclusion of NH4Cl [J].

Chen, Yani ;

Zhao, Yixin ;

Liang, Ziqi .

CHEMISTRY OF MATERIALS, 2015, 27 (05) :1448-1451

[8] Planar heterojunction perovskite/PC71BM solar cells with enhanced open-circuit voltage via a (2/1)-step spin-coating process [J].

Chiang, Chien-Hung ;

Tseng, Zong-Liang ;

Wu, Chun-Guey .

JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (38) :15897-15903

[9] Incorporation of Cl into sequentially deposited lead halide perovskite films for highly efficient mesoporous solar cells [J].

Dharani, Sabba ;

Dewi, Herlina Arianita ;

Prabhakar, Rajiv Ramanujam ;

Baikie, Tom ;

Shi, Chen ;

Du Yonghua ;

Mathews, Nripan ;

Boix, Pablo P. ;

Mhaisalkar, Subodh G. .

NANOSCALE, 2014, 6 (22) :13854-13860

[10] Effect of Annealing Temperature on Film Morphology of Organic-Inorganic Hybrid Pervoskite Solid-State Solar Cells [J].

Dualeh, Amalie ;

Tetreault, Nicolas ;

Moehl, Thomas ;

Gao, Peng ;

Nazeeruddin, Mohammad Khaja ;

Graetzel, Michael .

ADVANCED FUNCTIONAL MATERIALS, 2014, 24 (21) :3250-3258

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