The role of transition metal complexes in dye sensitized solar devices

被引：163

作者：

Bignozzi, C. A. ^{[1
]}

Argazzi, R. ^{[2
]}

Boaretto, R. ^{[1
]}

Busatto, E. ^{[1
]}

Carli, S. ^{[1
]}

Ronconi, F. ^{[1
]}

Caramori, S. ^{[1
]}

机构：

[1] Univ Ferrara, Dipartimento Chim, I-44121 Ferrara, Italy

[2] Ist Sintesi Organ & Fotoreattivita ISOF CNR, Dipartimento Chim, Rome, Italy

来源：

COORDINATION CHEMISTRY REVIEWS | 2013年 / 257卷 / 9-10期

关键词：

DSSC; Dye sensitizers; Electron transfer mediators; ELECTRON-TRANSFER MEDIATORS; NEAR-IR SENSITIZATION; HIGHLY EFFICIENT; ORGANIC-DYES; CONVERSION-EFFICIENCY; CHARGE RECOMBINATION; PHOTOELECTROCHEMICAL PROPERTIES; POLYPYRIDINE COMPLEXES; RUTHENIUM SENSITIZERS; REDOX REACTIONS;

D O I：

10.1016/j.ccr.2012.09.008

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This article focuses on the progress obtained in the design of metal complexes which find application as sensitizers for dye-sensitized solar cells, DSSCs, and as electron shuttles in substitution of the triiodide/iodide redox couple. Coupling of sterically hindered dyes with mobile shuttles, based on a transition metal complex, represents the most advanced innovation which has allowed to reach on a single device the record efficiency of 12%. Issues which require further research are also discussed. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：1472 / 1492

页数：21

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