Coordination chemistry, and catalytic conversions, of H2S

被引：32

作者：

James, BR

机构：

[1] Department of Chemistry, University of British Columbia, Vancouver

来源：

PURE AND APPLIED CHEMISTRY | 1997年 / 69卷 / 10期

基金：

匈牙利科学研究基金会; 加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1351/pac199769102213

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Some reactions of H2S with solutions of Pd- and Ru-phosphine complexes are described. The Pd systems involve sulfur abstraction and generation of H-2, catalytic conversions of H2S to H-2, and attempts to catalyse the (H2S --> H-2 + 'S') reaction. The Ru studies have led to crystallographic characterisation of a reversibly formed H2S complex, as well as more familiar oxidative addition-type chemistry of H2S. This lecture/review naturally emphasises work carried out at this University (UBC).

引用

收藏

页码：2213 / 2220

页数：8

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