The first efficient bovine serum albumin catalyzed asymmetric oxidation of tertiary amines to the corresponding N-oxides via kinetic dynamic resolution

被引：25

作者：

Colonna, S

Gaggero, N

Drabowicz, J

Lyzwa, P

Mikolajczyk, M

机构：

[1] Univ Milan, Fac Farm, Ctr CNR, I-2133 Milan, Italy

[2] Univ Milan, Fac Farm, Ist Chim Organ, I-2133 Milan, Italy

[3] Polish Acad Sci, Ctr Mol & Macromol Studies, PL-90363 Lodz, Poland

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 18期

关键词：

D O I：

10.1039/a905594k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Unsymmetrical teriary amines were oxidized with a few oxidants in the presence of bovine serum albumin to give the corresponding N-oxides of the highest optical purity ever reported (up to 66%) for the reaction of asymmetric oxidation of amines via their kinetic dynamic resolution.

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收藏

页码：1787 / 1788

页数：2

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