Self-organizing super-structures formed from hydrogen-bonded biimidazolate metal complexes

被引：100

作者：

Tadokoro, M ^{[1
]}

Kanno, H

Kitajima, T

Shimada-Umemoto, H

Nakanishi, N

Isobe, K

Nakasuji, K

机构：

[1] Osaka City Univ, Grad Sch Sci, Dept Chem, Sumiyoshi Ku, Osaka 5588585, Japan

[2] Osaka City Univ, Grad Sch Sci, Dept Mat Sci, Sumiyoshi Ku, Osaka 5588585, Japan

[3] Shizuoka Univ, Fac Sci, Dept Chem, Shizuoka 4228529, Japan

[4] Osaka Univ, Grad Sch Sci, Dept Chem, Toyonaka, Osaka 5600043, Japan

来源：

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA | 2002年 / 99卷 / 08期

关键词：

D O I：

10.1073/pnas.072661699

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

Manipulation of molecular crystals formed from self-organization is one of the important methods to develop the new molecular functional materials. In particular, we look upon mutual cohesive interactions of hydrogen bonding and metal coordination as one useful tool to construct the preprogramming superstructures. In this study, five controlled superstructures of a one-dimensional linear chain-a zigzag ribbon, right-handed and left-handed helices, and a two-dimensional honeycomb sheet-are newly created by using the neutral metal complexes with some 2,2'-biimidazolate mono-anions.

引用

页码：4950 / 4955

页数：6

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