Synthesis and X-ray single crystal structure of a bivalent glycocluster

被引：8

作者：

Tosin, M ^{[1
]}

Müller-Bunz, H ^{[1
]}

Murphy, PV ^{[1
]}

机构：

[1] Natl Univ Ireland Univ Coll Dublin, Dept Chem, Conway Inst Biomol & Biomed Res, Ctr Synth & Chem Biol, Dublin 4, Ireland

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 05期

关键词：

D O I：

10.1039/b313934d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structure of a bivalent glycocluster containing aromatic amides reveals that alkylation of secondary amides alters amide configuration and thus carbohydrate presentation. This also facilitates non covalent interactions (azide-azide, carbonyl-pyranose and aromatic-pyranose) and thus carbohydrate-carbohydrate stacking.

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收藏

页码：494 / 495

页数：2

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