Remarkable co-catalysis by copper(I) oxide in the palladium catalyzed cross-coupling of arylboronic acids with ethyl bromoacetate

被引：57

作者：

Liu, XX ^{[1
]}

Deng, MZ ^{[1
]}

机构：

[1] Acad Sinica, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 06期

关键词：

D O I：

10.1039/b111355k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Copper( I) oxide can effectively co-catalyze the Suzuki type cross-coupling reactions of arylboronic acids with ethyl bromoacetate. As an alternative protocol for introducing the methylenecarboxy group into functionalized molecules, this reaction occurs in the absence of highly toxic thallium compounds or special ligands and should be convenient and practical.

引用

收藏

页码：622 / 623

页数：2

相关论文

共 22 条

[1] TRANSITION-METAL CATALYZED-REACTIONS OF ORGANOZINC REAGENTS [J].

ERDIK, E .

TETRAHEDRON, 1992, 48 (44) :9577-9648

[2] Pd-catalyzed synthesis of arylacetic acid derivatives from boronic acids [J].

Goossen, LJ .

CHEMICAL COMMUNICATIONS, 2001, (07) :669-670

[3] DICHLORO[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]PALLADIUM-(II) - AN EFFECTIVE CATALYST FOR CROSS-COUPLING OF SECONDARY AND PRIMARY ALKYL GRIGNARD AND ALKYLZINC REAGENTS WITH ORGANIC HALIDES [J].

HAYASHI, T ;

KONISHI, M ;

KOBORI, Y ;

KUMADA, M ;

HIGUCHI, T ;

HIROTSU, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (01) :158-163

[4]

Heck R.F., 1985, PALLADIUM REAGENTS O

[5] NICKEL AND PALLADIUM COMPLEX CATALYZED CROSS-COUPLING REACTIONS OF ORGANOMETALLIC REAGENTS WITH ORGANIC HALIDES [J].

KUMADA, M .

PURE AND APPLIED CHEMISTRY, 1980, 52 (03) :669-679

[6] Synthesis of functionally substituted unsymmetrical biaryls via a novel double metal catalyzed coupling reaction [J].

Miller, JA ;

Farrell, RP .

TETRAHEDRON LETTERS, 1998, 39 (40) :7275-7278

[7]

MITCHELL TN, 1986, J ORGANOMET CHEM, V304, P1, DOI 10.1016/S0022-328X(00)99673-6

[8]

MITCHELL TN, 1992, SYNTHESIS-STUTTGART, P803

[9] PALLADIUM-CATALYZED CROSS-COUPLING REACTIONS OF ORGANOBORON COMPOUNDS [J].

MIYAURA, N ;

SUZUKI, A .

CHEMICAL REVIEWS, 1995, 95 (07) :2457-2483

[10] BIMETALLIC CATALYTIC-SYSTEMS CONTAINING TI, ZR, NI, AND PD - THEIR APPLICATIONS TO SELECTIVE ORGANIC SYNTHESES [J].

NEGISHI, E .

PURE AND APPLIED CHEMISTRY, 1981, 53 (12) :2333-2356