Copper-Catalyzed Intramolecular Electrophilic Carbofunctionalization of Allylic Amides

被引：102

作者：

Cahard, Elise ^{[1
]}

Bremeyer, Nadine ^{[1
]}

Gaunt, Matthew J. ^{[1
]}

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 35期

基金：

英国工程与自然科学研究理事会;

关键词：

copper; cyclization; diaryliodonium salts; homogeneous catalysis; oxazine; ENANTIOSELECTIVE ALPHA-ARYLATION; ONE-POT SYNTHESIS; DIARYLIODONIUM SALTS; ALKENE CARBOETHERIFICATION; CARBOAMINATION REACTIONS; ARYL PYRROLOINDOLINES; PALLADIUM; DERIVATIVES; BOND; GOLD;

D O I：

10.1002/anie.201303724

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An endo-selective copper-catalyzed oxyarylation and oxyvinylation of allylic amides was developed. The products are the six-membered ring oxazines and are formed exclusively as the antiisomers. A range of substituted allylic amides and a wide selection of diaryliodonium and vinyl(aryl)iodonium triflates are compatible with this transformation. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：9284 / 9288

页数：5

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