Modeling of the coastal boundary layer and pollutant transport in New England

Concentrations of ozone exceeding regulatory standards are regularly observed along the coasts of New Hampshire and Maine in summer. These events are primarily caused by the transport Of Pollutants from urban areas in Massachusetts and farther south and west. Pollutant transport is most efficient over the ocean. The coastline makes transport processes complex because it makes the Structure of the atmospheric boundary layer complex. During pollution episodes, the air over land in daytime is warmer than the sea surface, so air transported from land over water becomes statically stable and the formerly well-mixed boundary layer separates into possibly several layers, each transported in a different direction. This study examines several of the atmospheric boundary layer processes involved in pollutant transport. A three-dimensional model [the Coupled Ocean-Atmosphere Mesoscalc Prediction System (COAMPS)] run oil grids of 2.5 and 7.5 km is used to examine the winds, thermodynamic structure, and structure of tracer plumes emitted from Boston, Massachusetts, and New York City, New York, in two different real cases - one dominated by large-scale transport (22-23 July 2002) and one with important mesoscale effects (11-14 August 2002). The model simulations are compared with measurements taken during the 2002 New England Air Quality Study. The model simulates the basic Structure of the two different episodes well. The boundary layer stability over the cold water is weaker in the model than in reality. The tracer allows for easy visualization of the pollutant transport.