Interfaces between water splitting catalysts and buried silicon junctions

被引：54

作者：

Cox, Casandra R. ^{[1
]}

Winkler, Mark T. ^{[2
]}

Pijpers, Joep J. H. ^{[1
]}

Buonassisi, Tonio ^{[2
]}

Nocera, Daniel G. ^{[1
]}

机构：

[1] MIT, Dept Chem, Cambridge, MA 02139 USA

[2] MIT, Dept Mech Engn, Cambridge, MA 02139 USA

来源：

ENERGY & ENVIRONMENTAL SCIENCE | 2013年 / 6卷 / 02期

基金：

美国国家科学基金会;

关键词：

OXYGEN-EVOLVING CATALYST; NICKEL; CHEMISTRY; OXIDATION; DESIGN; PHOSPHATE; CRITERIA;

D O I：

10.1039/c2ee23932a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The coupling of water-splitting catalysts to silicon photovoltaics enables direct solar-to-fuel conversion. Critical to the performance of such devices is the use of interfaces to protect silicon from the oxygen-evolving reaction (OER) and at the same time to provide Ohmic contact between the buried silicon junction and the immobilised OER catalyst. Presented herein are guidelines for constructing the Si vertical bar catalyst interface, which is a crucial building block for efficient direct solar-to-fuel conversion devices. We show that fluorinated-tin-oxide is an especially attractive interface for buried-junction devices.

引用

收藏

页码：532 / 538

页数：7

相关论文

共 43 条

[1] Structure-Activity Correlations in a Nickel-Borate Oxygen Evolution Catalyst [J].

Bediako, D. Kwabena ;

Lassalle-Kaiser, Benedikt ;

Surendranath, Yogesh ;

Yano, Junko ;

Yachandra, Vittal K. ;

Nocera, Daniel G. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (15) :6801-6809

[2] Electronic design criteria for O-O bond formation via metal-oxo complexes [J].

Betley, Theodore A. ;

Wu, Qin ;

Van Voorhis, Troy ;

Nocera, Daniel G. .

INORGANIC CHEMISTRY, 2008, 47 (06) :1849-1861

[3] A ligand field chemistry of oxygen generation by the oxygen-evolving complex and synthetic active sites [J].

Betley, Theodore A. ;

Surendranath, Yogesh ;

Childress, Montana V. ;

Alliger, Glen E. ;

Fu, Ross ;

Cummins, Christopher C. ;

Nocera, Daniel G. .

PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY B-BIOLOGICAL SCIENCES, 2008, 363 (1494) :1293-1303

[4] Proton-coupled electron transfer: a unifying mechanism for biological charge transport, amino acid radical initiation and propagation, and bond making/breaking reactions of water and oxygen [J].

Chang, CJ ;

Chang, MCY ;

Damrauer, NH ;

Nocera, DG .

BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS, 2004, 1655 (1-3) :13-28

[5] TRANSPARENT CONDUCTORS - A STATUS REVIEW [J].

CHOPRA, KL ;

MAJOR, S ;

PANDYA, DK .

THIN SOLID FILMS, 1983, 102 (01) :1-46

[6] Making Oxygen with Ruthenium Complexes [J].

Concepcion, Javier J. ;

Jurss, Jonah W. ;

Brennaman, M. Kyle ;

Hoertz, Paul G. ;

Patrocinio, Antonio Otavio T. ;

Murakami Iha, Neyde Yukie ;

Templeton, Joseph L. ;

Meyer, Thomas J. .

ACCOUNTS OF CHEMICAL RESEARCH, 2009, 42 (12) :1954-1965

[7] Solar Energy Supply and Storage for the Legacy and Non legacy Worlds [J].

Cook, Timothy R. ;

Dogutan, Dilek K. ;

Reece, Steven Y. ;

Surendranath, Yogesh ;

Teets, Thomas S. ;

Nocera, Daniel G. .

CHEMICAL REVIEWS, 2010, 110 (11) :6474-6502

[8] THE CATALYSIS OF THE OXYGEN EVOLUTION REACTION BY IRON IMPURITIES IN THIN-FILM NICKEL-OXIDE ELECTRODES [J].

CORRIGAN, DA .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1987, 134 (02) :377-384

[9] Proton-coupled electron transfer [J].

Cukier, RI ;

Nocera, DG .

ANNUAL REVIEW OF PHYSICAL CHEMISTRY, 1998, 49 :337-369

[10] Molecular chemistry of consequence to renewable energy [J].

Dempsey, JL ;

Esswein, AJ ;

Manke, DR ;

Rosenthal, J ;

Soper, JD ;

Nocera, DG .

INORGANIC CHEMISTRY, 2005, 44 (20) :6879-6892

← 1 2 3 4 5 →