Liquid-crystalline elastomers

被引:170
作者
Terentjev, EM [1 ]
机构
[1] Univ Cambridge, Cavendish Lab, Cambridge CB3 0HE, England
关键词
D O I
10.1088/0953-8984/11/24/201
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Recent experimental and theoretical work shows that liquid-crystalline elastomers and gels have a highly mobile axis of anisotropy. Despite being nominally elastic solids, they also show features of fluids, such as the effect of soft elasticity. Work over the last few years is reviewed and some of the most important discoveries, as well as the outstanding problems in this field, are highlighted. We examine the unusual mechanical properties of nematic and smectic rubbers, their randomly disordered equilibrium textures, some aspects of dynamics and mechanical relaxation and the effect of uniform chiral piezoelectricity in amorphous polymer networks.
引用
收藏
页码:R239 / R257
页数:19
相关论文
共 72 条
[1]   LIQUID-CRYSTALLINE AND RIGID-ROD NETWORKS [J].
BARCLAY, GG ;
OBER, CK .
PROGRESS IN POLYMER SCIENCE, 1993, 18 (05) :899-945
[2]   MECHANICALLY INDUCED 2ND-HARMONIC GENERATION IN S-C-ASTERISK ELASTOMERS [J].
BENNE, I ;
SEMMLER, K ;
FINKELMANN, H .
MACROMOLECULES, 1995, 28 (06) :1854-1858
[3]   Liquid-crystalline main-chain elastomers [J].
Bergmann, GHF ;
Finkelmann, H ;
Percec, V ;
Zhao, MY .
MACROMOLECULAR RAPID COMMUNICATIONS, 1997, 18 (05) :353-360
[4]   DEFORMATION-INDUCED ORIENTATIONAL TRANSITIONS IN LIQUID-CRYSTALS ELASTOMER [J].
BLADON, P ;
TERENTJEV, EM ;
WARNER, M .
JOURNAL DE PHYSIQUE II, 1994, 4 (01) :75-91
[5]  
BRAND HR, 1998, HDB LIQUID CRYSTALS, V3, pCHR5
[6]   FERROELECTRIC LIQUID-CRYSTALLINE ELASTOMERS [J].
BREHMER, M ;
ZENTEL, R ;
WAGENBLAST, G ;
SIEMENSMEYER, K .
MACROMOLECULAR CHEMISTRY AND PHYSICS, 1994, 195 (06) :1891-1904
[7]   Coupling of liquid crystalline and polymer network properties in LC-elastomers [J].
Brehmer, M ;
Zentel, R ;
Giesselmann, F ;
Germer, R ;
Zugenmaier, P .
LIQUID CRYSTALS, 1996, 21 (04) :589-596
[8]   Ferroelectric LC-elastomers [J].
Brehmer, M ;
Zentel, R .
MACROMOLECULAR SYMPOSIA, 1997, 117 :53-56
[9]   Mechanical deformation behavior in highly anisotropic elastomers made from ferroelectric liquid crystalline polymers [J].
Brodowsky, HM ;
Boehnke, UC ;
Kremer, F ;
Gebhard, E ;
Zentel, R .
LANGMUIR, 1999, 15 (01) :274-278
[10]   Liquid crystalline epoxy based thermosetting polymers [J].
Carfagna, C ;
Amendola, E ;
Giamberini, M .
PROGRESS IN POLYMER SCIENCE, 1997, 22 (08) :1607-1647