The Liquefaction of Heracleum persicum by Supercritical Fluid Extraction

被引:14
作者
Aysu, T. [1 ]
Kucuk, M. M. [1 ]
机构
[1] Yuzuncu Yil Univ, Fac Educ, TR-65080 Van, Turkey
关键词
biomass; Heracleum persicum; Supercritical conversion of biomass; Supercritical fluid extraction; Synthetic fuels; BIOMASS CONVERSION; CELLULOSE;
D O I
10.1080/15567036.2011.636142
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
080707 [能源环境工程]; 082001 [油气井工程];
摘要
Milled Heracleum persicum stalk was converted to liquid products by using organic solvents (methanol, ethanol, acetone, and 2-butanol) with catalysts (10% NaOH or Na2CO3) and without catalyst in an autoclave at temperatures of 518, 538, and 558 K. The liquid products were extracted by liquid-liquid extraction (benzene and diethyl ether). The percentage yields from supercritical methanol, ethanol, 2-butanol, and acetone conversions were 49.1, 55.7, 58.7, and 71.0 at 558 K, respectively. In the catalytic run with NaOH, the highest conversion was obtained by using ethanol as a solvent at the same temperature. The yields of conversion were analyzed by GC-MS.
引用
收藏
页码:1787 / 1795
页数:9
相关论文
共 21 条
[1]
Appell H.R., 1967, FUELS WASTE
[2]
Direct liquefaction of biomass [J].
Behrendt, Frank ;
Neubauer, York ;
Oevermann, Michael ;
Wilmes, Birgit ;
Zobel, Nico .
CHEMICAL ENGINEERING & TECHNOLOGY, 2008, 31 (05) :667-677
[3]
Liquid products from Verbascum stalk by supercritical fluid extraction [J].
Cemek, M ;
Küçük, MM .
ENERGY CONVERSION AND MANAGEMENT, 2001, 42 (02) :125-130
[4]
Demirba A, 2010, ALGAE ENERGY
[5]
Effect of lignin content on aqueous liquefaction products of biomass [J].
Demirbas, A .
ENERGY CONVERSION AND MANAGEMENT, 2000, 41 (15) :1601-1607
[6]
Demirbas A, 2000, ENERG SOURCE, V22, P403
[7]
Mechanisms of liquefaction and pyrolysis reactions of biomass [J].
Demirbas, A .
ENERGY CONVERSION AND MANAGEMENT, 2000, 41 (06) :633-646
[8]
Demirbas A., 2000, ENERGY EDU SCI TECHN, V5, P21
[9]
CHEMICAL STUDIES ON OILS DERIVED FROM ASPEN POPLAR WOOD, CELLULOSE, AND AN ISOLATED ASPEN POPLAR LIGNIN [J].
EAGER, RL ;
PEPPER, JM ;
ROY, JC ;
MATHEWS, JF .
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1983, 61 (09) :2010-2015
[10]
CO2 mitigation and renewable oil from photosynthetic microbes: A new appraisal [J].
Huntley M.E. ;
Redalje D.G. .
Mitigation and Adaptation Strategies for Global Change, 2007, 12 (4) :573-608