Two simple precursor 2,2′-bisoxazoline complexes of ruthenium

被引：14

作者：

Pal, PK

Drew, MGB

Datta, D ^{[1
]}

机构：

[1] Indian Assoc Cultivat Sci, Dept Inorgan Chem, Kolkata 700032, W Bengal, India

[2] Univ Reading, Dept Chem, Reading RG6 6AD, Berks, England

来源：

NEW JOURNAL OF CHEMISTRY | 2002年 / 26卷 / 01期

关键词：

D O I：

10.1039/b109294b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Syntheses, X-ray crystal structures and some electrochemical properties of Ru-II L2Cl2, (RuL)-L-III(dimethylformamide)Cl-3 and [(RuL2Cl2)-L-II]PF6, where L is 4,4,4',4'-tetramethyl-2,2'-bisoxazoline, are described. It is found that the first two complexes serve as very good precursors to synthesise a host of mixed-ligand complexes of Ru(II) and Ru(III) containing L.

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页码：24 / 27

页数：4

相关论文

共 19 条

[1] Poly(ethylene glycol)-supported bisoxazolines as ligands for catalytic enantioselective synthesis [J].

Annunziata, R ;

Benaglia, M ;

Cinquini, M ;

Cozzi, F ;

Pitillo, M .

JOURNAL OF ORGANIC CHEMISTRY, 2001, 66 (09) :3160-3166

[2] 6-COORDINATE COMPLEXES WITH 1,10-PHENANTHROLINE LIGANDS IN THE TRANS CONFIGURATION - PREPARATION OF TRANS-BIS(1,10-PHENANTHROLINE)RUTHENIUM(II) COMPLEXES AND CRYSTAL-STRUCTURE OF TRANS-BIS(1,10-PHENANTHROLINE)BIS(PYRIDINE)RUTHENIUM(II) HEXAFLUOROPHOSPHATE [J].

BONNESON, P ;

WALSH, JL ;

PENNINGTON, WT ;

CORDES, AW ;

DURHAM, B .

INORGANIC CHEMISTRY, 1983, 22 (12) :1761-1765

[3] KINETICS OF OXIDATION OF BIS(PI-CYCLOPENTADIENYLDICARBONYLIRON) BY RU(BIPY)2CL2+ AND BY [(PI-C5H5)FE(CO)]4+ [J].

BRADDOCK, JN ;

MEYER, TJ .

INORGANIC CHEMISTRY, 1973, 12 (04) :723-727

[4]

BUTALA I, 1976, LIEBIGS ANN CHEM, P1455

[5] Enantioselective and diastereoselective mukaiyama-Michael reactions catalyzed by bis(oxazoline) Copper(II) complexes [J].

Evans, DA ;

Scheidt, KA ;

Johnston, JN ;

Willis, MC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (19) :4480-4491

[6] Nitrogen-containing ligands for asymmetric homogeneous and heterogeneous catalysis [J].

Fache, F ;

Schulz, E ;

Tommasino, ML ;

Lemaire, M .

CHEMICAL REVIEWS, 2000, 100 (06) :2159-2231

[7] Coordination chemistry of oxazoline ligands [J].

Gómez, M ;

Muller, G ;

Rocamora, M .

COORDINATION CHEMISTRY REVIEWS, 1999, 193-5 :769-835

[8] Chiral bis(oxazoline) copper(II) complexes: Versatile catalysts for enantioselective cycloaddition, aldol, Michael, and carbonyl ene reactions [J].

Johnson, JS ;

Evans, DA .

ACCOUNTS OF CHEMICAL RESEARCH, 2000, 33 (06) :325-335

[9] EVALUATION OF SINGLE-CRYSTAL X-RAY-DIFFRACTION DATA FROM A POSITION-SENSITIVE DETECTOR [J].

KABSCH, W .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1988, 21 (06) :916-924

[10] VALENCE LEVELS OF RU(II) AND OS(II) COMPLEXES STUDIED BY VOLTAMMETRY AND X-RAY PHOTOELECTRON-SPECTROSCOPY [J].

MATSUMURAINOUE, T ;

IKEMOTO, I ;

UMEZAWA, Y .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1986, 209 (01) :135-150