Iron(II)-8-quinolinol/MCM-41-catalyzed phenol hydroxylation and reaction mechanism

被引：60

作者：

Liu, CB ^{[1
]}

Shan, YJ ^{[1
]}

Yang, XG ^{[1
]}

Ye, XK ^{[1
]}

Wu, Y ^{[1
]}

机构：

[1] ACAD SINICA, CHANGCHUN INST APPL CHEM, CHANGCHUN 130022, PEOPLES R CHINA

来源：

JOURNAL OF CATALYSIS | 1997年 / 168卷 / 01期

关键词：

D O I：

10.1006/jcat.1997.1612

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Iron(II)-8-quinolino/MCM-41 is prepared. Its catalysis is studied in phenol hydroxylation using H2O2 (30%) as oxidant. The experiment shows that Iron(II)-8-quinolinol/MCM-41 has good catalytic activity and desired stability. Based on cyclic voltammetry, ESR, and UV-visible spectra studies of iron(II)-8-quinolinol complex in liquid phase, a radical substitution mechanism is proposed and used to demonstrate the experimental facts clearly. (C) 1997 Academic Press.

引用

页码：35 / 41

页数：7

共 33 条

[1] OLEFIN OXIDATION BY ZEOLITE-ENCAPSULATED MN(SALEN)+ COMPLEXES UNDER AMBIENT CONDITIONS [J].

BOWERS, C ;

DUTTA, PK .

JOURNAL OF CATALYSIS, 1990, 122 (02) :271-279

[2]

BRODSKII AI, 1962, ZH OBSHCH KHIM+, V32, P2273

[3]

CLERICI MG, 1991, APPL CATAL, V68, P249

[4] SYNTHESIS OF PROPYLENE-OXIDE FROM PROPYLENE AND HYDROGEN-PEROXIDE CATALYZED BY TITANIUM SILICALITE [J].

CLERICI, MG ;

BELLUSSI, G ;

ROMANO, U .

JOURNAL OF CATALYSIS, 1991, 129 (01) :159-167

[5] HYDROXYLATION SELECTIVITY OF PHENOL AND O-PROTECTED PHENOLS IN THE FE(III)-CATECHOL-H2O2 SYSTEM [J].

ELISEEV, AV ;

YATSIMIRSKII, AK .

REACTION KINETICS AND CATALYSIS LETTERS, 1991, 43 (02) :419-423

[6]

EREMEEV AP, 1980, ZH PRIKL KHIM, V53, P386

[7]

HOCKING MB, 1985, J CHEM TECH BIOT A, V35, P365

[8]

HUYBRECHTS DRC, 1991, CATAL LETT, V8, P273

[9]

JONES MM, 1968, LIGAND REACTIVITY CA, P99

[10] ORDERED MESOPOROUS MOLECULAR-SIEVES SYNTHESIZED BY A LIQUID-CRYSTAL TEMPLATE MECHANISM [J].

KRESGE, CT ;

LEONOWICZ, ME ;

ROTH, WJ ;

VARTULI, JC ;

BECK, JS .

NATURE, 1992, 359 (6397) :710-712

← 1 2 3 4 →