Adsorption and enthalpy of phenol on BPL carbon

被引：19

作者：

MacDonald, JAF ^{[1
]}

Evans, MJB ^{[1
]}

机构：

[1] Royal Mil Coll Canada, Dept Chem & Chem Engn, Kingston, ON KJK 7B4, Canada

来源：

CARBON | 2002年 / 40卷 / 05期

关键词：

activated carbon; adsorption; microcalorimetry; heat of adsorption;

D O I：

10.1016/S0008-6223(01)00187-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The displacement process of adsorption of phenol from aqueous solution on carbons with various surface properties has been studied using a flow calorimeter. The carbon surface was oxidised, chlorinated and treated with ethylene. The enthalpy of exchange of water with phenol was measured along with the quantitative uptake of phenol on a column of carbon from a flowing solution. It was determined that the uptake of phenol was primarily a pore filling phenomenon and surface alterations must be severe to have a significant influence on the enthalpy. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：703 / 707

页数：5

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