Bis(beta-diketonate) ligands for the synthesis of bimetallic complexes of Ti-III, V-III, Mn-III and Fe-III with a triple-helix structure

被引：64

作者：

Grillo, VA

Seddon, EJ

Grant, CM

Aromi, G

Bollinger, JC

Folting, K

Christou, G

机构：

[1] INDIANA UNIV,DEPT CHEM,BLOOMINGTON,IN 47405

[2] INDIANA UNIV,CTR MOL STRUCT,BLOOMINGTON,IN 47405

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 16期

关键词：

D O I：

10.1039/a702971c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Addition of the bis(beta-diketone) ligand L [L = 1,3-bis(3-phenyl-3-oxopropanoyl)benzene] to a suitable source of M-III ions (M = Ti, V, Mn, Fe) in a L:M = 3:2 ratio gives the dinuclear products [M2L3], which have a triple-helical structure.

引用

页码：1561 / 1562

页数：2

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