Stereoselective radical-radical coupling reactions of metallated imidazolines

被引：12

作者：

Dalko, PI ^{[1
]}

机构：

[1] Univ Paris Sud, Assoc CNRS, ICMO, Lab Synth Substances Nat, F-91405 Orsay, France

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 21期

关键词：

asymmetric reactions; carbanions; electron transfer; radicals and radical reactions;

D O I：

10.1016/S0040-4039(99)00664-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Dianions derived from chiral imidazolines 1a-c, undergo selective one-electron oxidation reactions in the presence of TEMPO (2,2,6,6-tetramethyl-1-piperidinyloxy) and form metallated radical species. Depending on the reaction conditions the radical intermediate is trapped stereoselectively by TEMPO, or undergoes a dimerization reaction. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：4035 / 4036

页数：2

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