Methanol-to-hydrocarbons: process technology

被引:423
作者
Keil, FJ [1 ]
机构
[1] Tech Univ Hamburg Harburg, Dept Chem Engn, D-21073 Hamburg, Germany
关键词
commercial plants; kinetics; methanol-to-gasoline; methanol-to-hydrocarbons; methanol-to-olefins; review;
D O I
10.1016/S1387-1811(98)00320-5
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
This review presents methanol-to-hydrocarbons processes which have reached industrial applications, either on a commercial or on a pilot plant scale. The determination of kinetic expressions for various methanol conversion reactions is given. The processes discussed are: Mobil's methanol-to-gasoline (MTG) plant in New Zealand, the fluidized bed MTG and methanol-to-olefins process; Mobil's olefin-to-gasoline/distillate (MOGD) process; the MTO plant developed by UOP and Norsk Hydro; Haldor Topsoe's TIGAS process. The developments of a liquid phase dimethyl ether synthesis (LP-DME) process by the Ahron University are also presented. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:49 / 66
页数:18
相关论文
共 57 条
[1]  
ALLUM KG, 1988, STUD SURF SCI CATAL, V36, P691
[2]   MECHANISM OF SOME CONVERSIONS OVER ZSM5 CATALYST [J].
ANDERSON, JR ;
MOLE, T ;
CHRISTOV, V .
JOURNAL OF CATALYSIS, 1980, 61 (02) :477-484
[3]  
[Anonymous], CHEM TECH OCT
[4]  
ANTHONY RG, 1981, CHEM ENG SCI, V36, P789
[5]  
Avidan A. A, 1988, STUD SURF SCI CAT, V36, P307, DOI DOI 10.1016/S0167-2991(09)60524-3
[6]  
BEM JZ, 1988, STUDIES SURFACE SCI, V36, P663
[7]   Concentration-dependent kinetic model for catalyst deactivation in the MTG process [J].
Benito, PL ;
Gayubo, AG ;
Aguayo, AT ;
Castilla, M ;
Bilbao, J .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1996, 35 (01) :81-89
[8]  
BIBBY DM, 1988, STUDIES SURFACE SCI, V36, P251
[9]   CONVERSION OF METHANOL TO LOWER OLEFINS - KINETIC MODELING, REACTOR SIMULATION, AND SELECTION [J].
BOS, ANR ;
TROMP, PJJ ;
AKSE, HN .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1995, 34 (11) :3808-3816
[10]   SYNGAS CONVERSION TO ETHANE OVER METAL ZEOLITE CATALYSTS [J].
CHANG, CD ;
MIALE, JN ;
SOCHA, RF .
JOURNAL OF CATALYSIS, 1984, 90 (01) :84-87