Structure and reactions of a metallacyclic complex containing a remarkably long uranium-carbon bond

被引：51

作者：

Boaretto, R ^{[1
]}

Roussel, P ^{[1
]}

Kingsley, AJ ^{[1
]}

Munslow, IJ ^{[1
]}

Sanders, CJ ^{[1
]}

Alcock, NW ^{[1
]}

Scott, P ^{[1
]}

机构：

[1] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 17期

关键词：

D O I：

10.1039/a903783g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The intramolecular metalation of a beta-silyl methyl group in [U{N(CH2CH2NSiMe2But)(3)}(CH2Ph)] occurs rapidly, despite the conformational demands of the triamidoamine ligand, to produce a highly strained metallacycle (U-C ca. 2.75 Angstrom); this complex reacts cleanly with a range of carbon and other acids to give, for example, an alkynyl with a bent (156 degrees) U-C=C unit.

引用

页码：1701 / 1702

页数：2

共 34 条

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