Natural abundance H-2 nuclear magnetic resonance study of the origin of n-hexanol

被引：5

作者：

Fronza, G

Fuganti, C

Zucchi, G

Barbeni, M

Cisero, M

机构：

[1] POLITECN MILAN, CNR, CTR CHIM SOSTANZE ORGAN NAT, DIPARTIMENTO CHIM, I-20131 MILAN, ITALY

[2] SAN GIORGIO FLAVORS, I-10147 TURIN, ITALY

来源：

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY | 1996年 / 44卷 / 03期

关键词：

SNIF-NMR; aromas; n-hexanol; authentication;

D O I：

10.1021/jf950514v

中图分类号：

S [农业科学];

学科分类号：

09 ;

摘要：

The site-specific natural abundance deuterium distribution of hexanol (1) obtained through a variety of methods has been determined through H-2 NMR spectroscopy. This study, actually performed on the acetate ester 3, provides a means of distinguishing between ''natural'' materials isolated from natural sources or obtained by Colletotrichum gloeosporioides mediated reduction of natural hexanoic acid and other products of synthetic origin or produced from hexanoic acid by LiAlH4 reduction. Particularly significant were the variations of the molar fraction values at position 1 with respect to positions 3, 4, and 5.

引用

页码：887 / 891

页数：5

共 16 条

[1] FRACHIMONT A, 1872, LIEBIGS ANN CHEM, V163, P193
[2] NATURAL-ABUNDANCE H-2 NUCLEAR-MAGNETIC-RESONANCE STUDY OF THE ORIGIN OF 2-PHENYLETHANOL AND 2-PHENYLETHYL ACETATE
FRONZA, G
FUGANTI, C
GRASSELLI, P
SERVI, S
ZUCCHI, G
BARBENI, M
CISERO, M
[J]. JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1995, 43 (02) : 439 - 443
[3] REDUCTION OF CARBOXYLATES TO ALKANOLS CATALYZED BY COLLETOTRICHUM GLOEOSPOROIDES
FRONZA, G
FUGANTI, C
GRASSELLI, P
SERVI, S
ZUCCHI, G
BARBENI, M
VILLA, M
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (04) : 439 - 440
[4] NATURAL ABUNDANCE H-2 NUCLEAR-MAGNETIC-RESONANCE STUDY OF THE ORIGIN OF (R)-DELTA-DECANOLIDE
FRONZA, G
FUGANTI, C
GRASSELLI, P
BARBENI, M
CISERO, M
[J]. JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1993, 41 (02) : 235 - 239
[5] FUGANTI C, 1993, STUDIES NATURAL PROD, V13, P295
[6] STANDARDS FOR STABLE ISOTOPE MEASUREMENTS IN NATURAL COMPOUNDS
GONFIANTINI, R
[J]. NATURE, 1978, 271 (5645) : 534 - 536
[7] NMR DETERMINATION OF SITE-SPECIFIC DEUTERIUM-ISOTOPE EFFECTS
GRANT, DM
CURTIS, J
CROASMUN, WR
DALLING, DK
WEHRLI, FW
WEHRLI, S
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (16) : 4492 - 4494
[8] DIFFERENTIATION OF NATURAL AND SYNTHETIC BENZALDEHYDES BY H-2 NUCLEAR-MAGNETIC-RESONANCE
HAGEDORN, ML
[J]. JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1992, 40 (04) : 634 - 637
[9] THE BIOGENERATION OF GREEN ODOR BY GREEN LEAVES
HATANAKA, A
[J]. PHYTOCHEMISTRY, 1993, 34 (05) : 1201 - 1218
[10] A NEW METHOD FOR THE IDENTIFICATION OF THE ORIGIN OF NATURAL-PRODUCTS - QUANTITATIVE H-2 NMR AT THE NATURAL ABUNDANCE LEVEL APPLIED TO THE CHARACTERIZATION OF ANETHOLES
MARTIN, GJ
MARTIN, ML
MABON, F
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (09) : 2658 - 2659

← 1 2 →