[Mg(thf)(4)](2+): The first gas-phase evidence of a stable multiply charged metal-ligand unit

被引：13

作者：

Dobson, MP ^{[1
]}

Stace, AJ ^{[1
]}

机构：

[1] UNIV SUSSEX, SCH MOLEC SCI, BRIGHTON BN1 9QJ, E SUSSEX, ENGLAND

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 13期

关键词：

D O I：

10.1039/cc9960001533

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The preparation and study of gas-phase clusters in the form of solvated multiply charged metal ions presents a considerable experimental challenge; these first results on [Mg(thf)(4)](2+) suggest that stability is due primarily to orbital overlap rather than electrostatic interactions.

引用

页码：1533 / 1534

页数：2

共 17 条

[1] STUDIES OF ALKALINE-EARTH AND TRANSITION-METAL M++ GAS-PHASE ION CHEMISTRY [J].

BLADES, AT ;

JAYAWEERA, P ;

IKONOMOU, MG ;

KEBARLE, P .

JOURNAL OF CHEMICAL PHYSICS, 1990, 92 (10) :5900-5906

[2] ION-MOLECULE CLUSTERS INVOLVING DOUBLY CHARGED METAL-IONS (M2+) [J].

BLADES, AT ;

JAYAWEERA, P ;

IKONOMOU, MG ;

KEBARLE, P .

INTERNATIONAL JOURNAL OF MASS SPECTROMETRY AND ION PROCESSES, 1990, 102 :251-267

[3]

Cooks RG., 1973, Metastable Ions

[4]

Cotton F.A., 1988, Advanced Inorganic Chemistry

[5] A STUDY OF THE MGCL2-TETRAHYDROFURAN SYSTEM [J].

HANDLIR, K ;

HOLECEK, J ;

BENES, L .

COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1985, 50 (11) :2422-2430

[6] PRODUCTION AND STUDY IN THE GAS-PHASE OF MULTIPLY CHARGED SOLVATED OR COORDINATED METAL-IONS [J].

JAYAWEERA, P ;

BLADES, AT ;

IKONOMOU, MG ;

KEBARLE, P .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (06) :2452-2454

[7] LASER-INDUCED INFRARED PHOTOFRAGMENTATION OF SF6(C6H6)(N)(+) CLUSTER IONS [J].

JONES, AB ;

LOPEZMARTENS, R ;

STACE, AJ .

JOURNAL OF PHYSICAL CHEMISTRY, 1995, 99 (17) :6333-6339

[8] COMPLEXES OF (PHENAZINE)-. AND (PHENAZINE)2- WITH MAGNESIUM(II) SYNTHESES OF [MG(C12H8N2)2(TETRAHYDROFURAN)3], [MG(C12H8N2)(TETRAHYDROFURAN)2], AND [MG2BR2(C12H8N2)(TETRAHYDROFURAN)6].[MGBR2(THF)4] (X-RAY AUTHENTICATED) [J].

JUNK, PC ;

RASTON, CL ;

SKELTON, BW ;

WHITE, AH .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (15) :1162-1164

[9]

Kebarle P., 1977, ANNU REV PHYS CHEM, V74, P1466

[10] THERMOCHEMICAL DATA ON GAS-PHASE ION-MOLECULE ASSOCIATION AND CLUSTERING REACTIONS [J].

KEESEE, RG ;

CASTLEMAN, AW .

JOURNAL OF PHYSICAL AND CHEMICAL REFERENCE DATA, 1986, 15 (03) :1011-1071

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