N-heterocyclic carbenes:: novel ruthenium-alkylidene complexes

被引：126

作者：

Weskamp, T ^{[1
]}

Kohl, FJ ^{[1
]}

Herrmann, WA ^{[1
]}

机构：

[1] Tech Univ Munich, Inst Anorgan Chem, D-85747 Garching, Germany

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1999年 / 582卷 / 02期

关键词：

N-heterocyclic carbenes; ruthenium; homogeneous catalysis; olefin metathesis;

D O I：

10.1016/S0022-328X(99)00163-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Ruthenium-based catalysts for olefin metathesis have attained enormous attention during the past years. Recently we have shown that the application of N-heterocyclic carbenes extends and complements the ubiquitous phosphanes. We now report on new members of our family of ruthenium-based catalysts for olefin metathesis. The synthesis of novel mixed carbene/phosphane- and homo- and heterobimetallic rutheniumalkylidene complexes is presented. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：362 / 365

页数：4

共 18 条

[1] [Anonymous], ANGEW CHEM
[2] A STABLE CRYSTALLINE CARBENE
ARDUENGO, AJ
HARLOW, RL
KLINE, M
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (01) : 361 - 363
[3] Synthesis and investigation of homo- and heterobimetallic ruthenium olefin metathesis catalysts exhibiting increased activities
Dias, EL
Grubbs, RH
[J]. ORGANOMETALLICS, 1998, 17 (13) : 2758 - 2767
[4] N-heterocyclic carbenes.: 19 -: Dicationic chelating N-heterocyclic carbene complexes of palladium:: new catalysts for the copolymerisation of C2H4 and CO
Gardiner, MG
Herrmann, WA
Reisinger, CP
Schwarz, J
Spiegler, M
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 572 (02) : 239 - 247
[5] Herrmann W., 1997, Angew. Chem. Int. Ed. Engl, V109, P2256
[6] Herrmann W. A., 1995, ANGEW CHEM, V107, P2602
[7] Heterocyclic carbenes: A high-yielding synthesis of novel, functionalized N-heterocyclic carbenes in liquid ammonia
Herrmann, WA
Kocher, C
Goossen, LJ
Artus, GRJ
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 1996, 2 (12) : 1627 - 1636
[8] N-heterocyclic carbenes
Herrmann, WA
Kocher, C
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1997, 36 (20) : 2162 - 2187
[9] Chiral heterocyclic carbenes in asymmetric homogeneous catalysis
Herrmann, WA
Goossen, LJ
Kocher, C
Artus, GRJ
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (23-24): : 2805 - 2807
[10] N-heterocyclic carbenes([+]): Generation under mild conditions and formation of group 8-10 transition metal complexes relevant to catalysis
Herrmann, WA
Elison, M
Fischer, J
Kocher, C
Artus, GRJ
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 1996, 2 (07) : 772 - 780

← 1 2 →