Lewis acid catalyzed sulfur transfer from a sultene to strained cyclic alkenes

被引：8

作者：

Adam, W ^{[1
]}

Fröhling, B ^{[1
]}

机构：

[1] Univ Wurzburg, Inst Organ Chem, D-97974 Wurzburg, Germany

来源：

ORGANIC LETTERS | 2002年 / 4卷 / 04期

关键词：

D O I：

10.1021/ol017203s

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] Sultene 1 reacts with cyclic alkenes under mild Lewis acid catalysis to form thiiranes diastereoselectively. With 1-methoxycyclooctene as sulfur acceptor, an unexpected insertion product is formed, which provides valuable mechanistic insight into the sulfur-transfer process.

引用

页码：599 / 602

页数：4

共 6 条

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