Lewis acid catalyzed sulfur transfer from a sultene to strained cyclic alkenes

被引:8
作者
Adam, W [1 ]
Fröhling, B [1 ]
机构
[1] Univ Wurzburg, Inst Organ Chem, D-97974 Wurzburg, Germany
关键词
D O I
10.1021/ol017203s
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
[GRAPHICS] Sultene 1 reacts with cyclic alkenes under mild Lewis acid catalysis to form thiiranes diastereoselectively. With 1-methoxycyclooctene as sulfur acceptor, an unexpected insertion product is formed, which provides valuable mechanistic insight into the sulfur-transfer process.
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页码:599 / 602
页数:4
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