Role of a chromium ion implantation on the corrosion behaviour of nickel in artificial sea water

被引:21
作者
Grosseau-Poussard, JL [1 ]
Dinhut, JF
Silvain, JF
Sabot, R
机构
[1] Univ La Rochelle, Pole Sci & Technol, Lab Etud Mat Milieux Agress, F-17042 La Rochelle 1, France
[2] Univ Bordeaux 1, CNRS, ICMCB, F-33608 Pessac, France
关键词
X-ray photoelectron spectroscopy; implantation; passive films; sea water; nickel;
D O I
10.1016/S0169-4332(99)00257-3
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Ni bulk specimens have been implanted with Cr ions (60 keV, 4.10(16) ions/cm(2)), and classical corrosion experiments performed in artificial sea water by means of potentiodynamics i(E) and potentiostatics i(t) studies. Both experiments show that an important decrease of the current density is obtained in comparison with pure nickel. Moreover, a significant extension of the passivation region can be observed, with mainly an increase of the pitting potential. This behaviour is respectively related to an X-ray photoelectron spectroscopy (XPS) analysis of the passive film formed on Ni (Ni, Cr and O environments), and to previous results obtained on similar alloys. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:49 / 62
页数:14
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