On the supramolecular organization of Langmuir-Blodgett cellulose acetovalerate films

被引:5
作者
Feigin, L
Klechkovskaya, V
Stepina, N
Tolstikhina, A
Khripunov, A
Baklagina, Y
Volkov, A
Antolini, R
机构
[1] Russian Acad Sci, Inst Crystallog, Moscow 117333, Russia
[2] Russian Acad Sci, Inst Macromol Cpds, St Petersburg 199004, Russia
[3] Univ Trent, INFM, I-38050 Povo, TN, Italy
[4] Univ Trent, Dept Phys, I-38050 Povo, TN, Italy
关键词
cellulose acetovulerate; Langmuir-Blodgett films; X-ray scattering; electron diffraction; atomic force microscopy;
D O I
10.1016/S0927-7757(01)00909-8
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The conditions of the deposition of the mixed cellulose acetovalerate ester Langmuir-Blodgett (LB) films are studied. The structure of films is examined by X-ray and electron diffraction methods, and atomic force microscopy. It was shown that LB films reveal the Y-type layer structure. A comparison between the macromolecule packing in LB films and macrofilms (bulk) was done. Modeling of the cellulose acetovaterate mono- and multilayer organization on the basis of the pi-A isotherms and structural data was realized. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:13 / 19
页数:7
相关论文
共 8 条
[1]   HIGH-RESOLUTION SOLID-STATE C-13 NUCLEAR MAGNETIC-RESONANCE SPECTROSCOPY OF TUNICIN, AN ANIMAL CELLULOSE [J].
BELTON, PS ;
TANNER, SF ;
CARTIER, N ;
CHANZY, H .
MACROMOLECULES, 1989, 22 (04) :1615-1617
[2]   The biosynthesis of cellulose [J].
Brown, RM .
JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, 1996, A33 (10) :1345-1373
[3]  
Bushin SV, 1999, VYSOKOMOL SOEDIN, V41, P1021
[4]   MONOMOLECULAR AND MULTIMOLECULAR FILMS OF CELLULOSE ESTERS WITH VARIOUS ALKYL CHAINS [J].
KAWAGUCHI, T ;
NAKAHARA, H ;
FUKUDA, K .
THIN SOLID FILMS, 1985, 133 (1-4) :29-38
[5]   Model of packing of cellulose acetomyristinate in Langmuir-Blodgett films [J].
Khripunov, AK ;
Baklagina, YG ;
Stepina, ND ;
Yanusova, LG ;
Feigin, LA ;
Denisov, VM ;
Volkov, AY ;
Lavrent'ev, VK .
CRYSTALLOGRAPHY REPORTS, 2000, 45 (02) :318-322
[6]   CELLULOSE BIOSYNTHESIS AND FUNCTION IN BACTERIA [J].
ROSS, P ;
MAYER, R ;
BENZIMAN, M .
MICROBIOLOGICAL REVIEWS, 1991, 55 (01) :35-58
[7]   ULTRATHIN LAYERS AND SUPRAMOLECULAR ARCHITECTURE OF ISOPENTYLCELLULOSE [J].
SCHAUB, M ;
FAKIROV, C ;
SCHMIDT, A ;
LIESER, G ;
WENZ, G ;
WEGNER, G ;
ALBOUY, PA ;
WU, H ;
FOSTER, MD ;
MAJKRZAK, C ;
SATIJA, S .
MACROMOLECULES, 1995, 28 (04) :1221-1228
[8]  
TSVETKOV NV, 1995, VYSOKOMOL SOEDIN, V37, P1306