Synthesis and structure of [bis(pyrazol-1-yl)acetato]trioxorhenium(VII) and [bis(3,5-dimethylpyrazol-1-yl)acetato]trioxorhenium(VII)

被引：31

作者：

Burzlaff, N ^{[1
]}

Hegelmann, I ^{[1
]}

机构：

[1] Univ Konstanz, Fachbereich Chem, D-78457 Constance, Germany

来源：

INORGANICA CHIMICA ACTA | 2002年 / 329卷

关键词：

rhenium; trioxorhenium; bis(pyrazol-1-yl)acetate; scorpionate; perrhenic acid;

D O I：

10.1016/S0020-1693(01)00784-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The coordination of the ligands bis(pyrazol-1-yl)acetate (bpza) and bis(3,5-dimethylpy razol-1-yl) acetate (bdmpza) to rhenium(VII) was investigated. The compounds [(bpza)ReO3] and [(bdmpza)ReO3] were synthesised by reaction of bpza and bdmpza with perrhenic acid with the loss of one water molecule. The new complex [(bdmpza)ReO3] was characterised by single-crystal X-ray analysis. It has a monomeric structure with a distorted octahedron for the [N,N,O]ReO3 central core. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：147 / 150

页数：4

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