Eu-151 Mossbauer spectroscopic, electric, and magnetic measurements of EuAgGe and EuAuGe

The physical properties of EuAgGe and EuAuGe, the structures of which are derived from the CeCu2 type, have been investigated in detail by means of magnetic susceptibility, electrical conductivity and Eu-151 Mossbauer measurements. Above 50 K both germanides show Curie-Weiss behavior with experimental magnetic moments of mu(exp) = 7.70(5) mu(B) (EuAgGe) and mu(exp), = 7.40(5) mu(B) (EuAuGe) and Weiss constants of -2(1) K (EuAgGe) and 33(1) K (EuAuCe). For EuAgGe, a magnetic phase transition is observed below 18(1) K. Zero-field cooling and field cooling measurements indicate cluster glass behavior (weak ferromagnetism, mictomagnetism). Magnetization measurements at 5 K show a saturation magnetic moment of 3.3(2) mu(B)/Eu at 5.5 T. Eu-151 Mossbauer measurements show a Eu(II) valence state (delta = -10.4 mm/s). While magnetic hyperfine splitting appears in the spectra at temperatures as high as 15 K, complete magnetic ordering is not reached at temperatures down to 4.2 K. EuAuGe orders ferromagnetically at 32.9(2) K. Magnetization measurements at 2 K show a saturation magnetic moment of 6.2(1) mu(B)/EU at 5.5 T, respectively indicating that all spins are ordered ferromagnetically at low temperatures. (EU)-E-151 Mossbauer measurements show a Eu(II) valence state (delta = -10.6 mm/s) and two spectral components in an approximate 1:1 ratio, subjected to magnetic hyperfine splitting effects at T-1 = 32(2) and T-2 = 18(4) K, respectively. Thus, the transition temperature of 32.9 K observed in the susceptibility measurements appears to be associated with ordering of only one of the two crystallographical ly distinct europium sites in this compound. Electrical conductivity measurements indicate metallic behavior for both germanides.