From Solvolysis to Self-Assembly

被引：59

作者：

Stang, Peter J. ^{[1
]}

机构：

[1] Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2009年 / 74卷 / 01期

基金：

美国国家科学基金会;

关键词：

X-RAY CRYSTAL; EXTENDED UNSATURATED CARBENES; SCANNING-TUNNELING-MICROSCOPY; SUBSTITUTED VINYL CATIONS; IODONIUM-TRANSITION-METAL; ACID-CATALYZED HYDRATION; CROSS-COUPLING REACTIONS; C-H INSERTION; FUNCTIONALIZED ALKYNYL(PHENYL)IODONIUM SALTS; SUPRAMOLECULAR-TRUNCATED TETRAHEDRA;

D O I：

10.1021/jo801682d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

My sojourn from classical physical-organic chemistry and solvolysis to self-assembly and supramolecular chemistry, over the last forty years, is described. My contributions to unsaturated reactive intermediates, namely vinyl cations and unsaturated carbenes, along with my decade-long involvement with polyvalent iodine chemistry, especially alkynyliodonium salts, as well as my more recent research with metal-ligand. coordination driven, and directed self-assembly of finite supramolecular ensembles are discussed.

引用

页码：2 / 20

页数：19

共 562 条

[1] Synthesis of a bis(pyridyl)-substituted perylene diimide ligand and incorporation into a supramolecular rhomboid and rectangle via coordination driven self-assembly [J].