Photocatalytic activity of high-vacuum annealed CdS-TiO2 thin film

被引:25
作者
Biswas, S. [1 ]
Hossain, M. F. [2 ]
Takahashi, T. [2 ]
Kubota, Y. [3 ]
Fujishima, A. [4 ]
机构
[1] Toyama Univ, Venture Business Lab, Toyama 9308555, Japan
[2] Toyama Univ, Grad Sch Sci & Engn Res, Toyama 9308555, Japan
[3] Yokohama City Univ, Grad Sch Med, Dept Urol & Mol Sci, Kanazawa Ku, Kanagawa 2360004, Japan
[4] Kanagawa Acad Sci & Technol, Kanagawa 2130012, Japan
基金
日本学术振兴会;
关键词
photocatalysis; chemical bath deposition; titanium oxide;
D O I
10.1016/j.tsf.2008.01.006
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
CdS-TiO2 thin film heterojunctions were prepared on glass and indium, tin oxide (ITO) substrates with the aim of improving photocatalytic efficiency both in UV-visible and visible light irradiation. The CdS under-layers were prepared by chemical bath deposition technique and subsequently they were annealed in the high vacuum of 5 x 10(-5) Pa at the temperature of 400 degrees C. The structural and optical properties of all the CdS-TiO2 thin films were studied with the help of X-ray diffractometer, atomic force microscope and ultraviolet-visible spectrophotometer. The photocatalytic activity of the thin films was evaluated by the decomposition of methanol by the use of fourier transform infrared spectrophotometer. It is revealed that the use of ITO substrate and high-vacuum annealing after deposition significantly enhance photocatalytic activity. (c) 2008 Elsevier B.V All rights reserved.
引用
收藏
页码:7313 / 7317
页数:5
相关论文
共 27 条
[1]   Photoluminescence studies of US thin films annealed in CdCl2 atmosphere [J].
Aguilar-Hernández, J ;
Sastré-Hernández, J ;
Mendoza-Pérez, R ;
Contreras-Puente, G ;
Cárdenas-García, M ;
Ortiz-López, J .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2006, 90 (06) :704-712
[2]  
Anpo M, 1997, WS PHOTOSCI PHOTOENG, V3, P133
[3]   Design of unique titanium oxide photocatalysts by an advanced metal ion-implantation method and photocatalytic reactions under visible light irradiation [J].
Anpo, M ;
Ichihashi, Y ;
Takeuchi, M ;
Yamashita, H .
RESEARCH ON CHEMICAL INTERMEDIATES, 1998, 24 (02) :143-149
[4]   UV-vis versus visible degradation of Acid Orange II in a coupled CdS/TiO2 semiconductors suspension [J].
Bessekhouad, Y. ;
Chaoui, N. ;
Trzpit, M. ;
Ghazzal, N. ;
Robert, D. ;
Weber, J. V. .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2006, 183 (1-2) :218-224
[5]   Determination of band edge energies for transparent nanocrystalline TiO2-CdS sandwich electrodes prepared by electrodeposition [J].
Flood, R ;
Enright, B ;
Allen, M ;
Barry, S ;
Dalton, A ;
Doyle, H ;
Tynan, D ;
Fitzmaurice, D .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 1995, 39 (01) :83-98
[6]   ELECTROCHEMICAL PHOTOLYSIS OF WATER AT A SEMICONDUCTOR ELECTRODE [J].
FUJISHIMA, A ;
HONDA, K .
NATURE, 1972, 238 (5358) :37-+
[7]   Competitive paths for methanol decomposition on Pt(111) [J].
Greeley, J ;
Mavrikakis, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (12) :3910-3919
[8]   ENVIRONMENTAL APPLICATIONS OF SEMICONDUCTOR PHOTOCATALYSIS [J].
HOFFMANN, MR ;
MARTIN, ST ;
CHOI, WY ;
BAHNEMANN, DW .
CHEMICAL REVIEWS, 1995, 95 (01) :69-96
[9]   Optimization of CdS/TiO2 nano-bulk composite photocatalysts for hydrogen production from Na2S/Na2SO3 aqueous electrolyte solution under visible light (λ ≥ 420 nm) [J].
Jang, Jum Suk ;
Ji, Sang Min ;
Bae, Sang Won ;
Son, Hyo Chang ;
Lee, Jae Sung .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2007, 188 (01) :112-119
[10]   TiO2@CdS core-shell nanorods films:: Fabrication and dramatically enhanced photoelectrochemical properties [J].
Jia, Huimin ;
Xu, Hua ;
Hu, Yan ;
Tang, Yiwen ;
Zhang, Lizhi .
ELECTROCHEMISTRY COMMUNICATIONS, 2007, 9 (03) :354-360