Preparation and molecular structures of FcCCI and {Co2(CO)6}2(μ:μ-FcC2C2Fc) [Fc = ferrocenyl, (η-C5H4)Fe(η-C5H5)]

被引：22

作者：

Bruce, MI ^{[1
]}

Skelton, BW

Smith, ME

White, AH

机构：

[1] Univ Adelaide, Dept Chem, Adelaide, SA 5005, Australia

[2] Univ Western Australia, Dept Chem, Nedlands, WA 6907, Australia

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1999年 / 52卷 / 06期

关键词：

D O I：

10.1071/CH99024

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Iodination of FcC=CH with morpholinium iodide gave structurally characterized iodoethynylferrocene, FcC=CI; its reaction with Co-2(CO)(8) affords {Co-2(CO)(6)}(2)(mu:mu-FcC(2)C(2)Fc), also characterized by an X-ray structure determination. This compound is formed by deiodinative coupling of the iodoalkyne and subsequent addition of a Co-2(CO)(6) group to each C=C triple bond in the resulting diyne.

引用

页码：431 / 435

页数：5

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