Enantioselective synthesis of the individual stereoisomers of a brassinolide mimetic

被引：6

作者：

Back, TG

Bey, MA

Parvez, M

Pharis, RP

机构：

[1] Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada

[2] Univ Calgary, Dept Biol Sci, Calgary, AB T2N 1N4, Canada

来源：

TETRAHEDRON-ASYMMETRY | 2004年 / 15卷 / 05期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1016/j.tetasy.2004.01.029

中图分类号：

O61 [无机化学];

学科分类号：

070301 [无机化学]; 081704 [应用化学];

摘要：

The syntheses of all four stereoisomers of a nonsteroidal mimetic of the phytohormone brassinolide are reported. These re: (+)-(6S,7R,6'S,7'R)-, (-)-(6R,7S,6'R,7'S)-, (+)-(6S,7R,6'R,7'S)-, and (-)-(6R,7S,6'S,7'R)-1-[1-(4,6,7-trihydroxy-5,6,7,8-tetrahydronaphthyl)]-2-[1'-(6',7'-dihydroxy-5',6',7',8'-tetrahydronaphthyl)]ethyne. (C) 2004 Elsevier Ltd. All rights reserved.

引用

收藏

页码：873 / 880

页数：8

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