An uncommon bonding mode of a familiar ligand:: a molybdenum complex with a four-electron donor chelating η3-PPh3 ligand, and its structural determination using synchrotron radiation

被引：31

作者：

Cheng, TY ^{[1
]}

Szalda, DJ ^{[1
]}

Bullock, RM ^{[1
]}

机构：

[1] Brookhaven Natl Lab, Dept Chem, Upton, NY 11973 USA

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 17期

关键词：

D O I：

10.1039/a905092b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A crystallographic study using synchrotron radiation shows that a C=C bond of one phenyl group of a PPh3 ligand bonds to Mo in [Cp(CO)(2)(PPh3)Mo](+), resulting in an unusual bonding mode in which PPh3 functions as a chelating four-electron donor ligand.

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页码：1629 / 1630

页数：2

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