A novel 2D luminescent lead(II) framework with 3-carboxylic acid-4H-1,2,4-triazole based on binuclear Pb2Cl2(H2O)2 building blocks

被引：35

作者：

Ding, Bin ^{[1
]}

Yang, En-Cui ^{[1
]}

Guo, Jian-Hua ^{[1
]}

Zhao, Xiao-Jun ^{[1
]}

Wang, Xiu-Guang ^{[1
]}

机构：

[1] Tianjin Normal Univ, Coll Chem & Life Chem, Tianjin 300387, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2008年 / 11卷 / 12期

关键词：

3-Carboxylic acid-4H-1,2,4-triazole; Pb2Cl2(H2O)(2); Tetra-dentate; Fluorescence;

D O I：

10.1016/j.inoche.2008.10.012

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Under hydrothermal conditions using a triazole derivative ligand 3-carboxylic acid-4H-1,2,4-triazole (HL) and corresponding lead(II) salts, a novel two-dimensional(2D) lead(II) complex {[Pb(L)(mu(2)-Cl)(H2O)}(n) (1) has been isolated. In 1 Pb2Cl2(H2O)(2) building blocks can be observed, which are extended by tetra-dentate coordinated L ligands to form a 2D corrugated layered structure. 1 also represents a novel example of luminescent lead(II) frameworks with triazole derivatives. Solid-state fluorescence spectrum of 1 exhibits the excited peak at 376 nm while the emission peak at 604 nm. (c) 2008 Elsevier B.V. All rights reserved.

引用

页码：1481 / 1483

页数：3

共 22 条

[1] Metal aminocarboxylate coordination polymers with chain and layered structures [J].

Dan, M ;

Rao, CNR .

CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (23) :7102-7109

[2] RELATIONSHIPS BETWEEN THE CARBON-OXYGEN STRETCHING FREQUENCIES OF CARBOXYLATO COMPLEXES AND THE TYPE OF CARBOXYLATE COORDINATION [J].

DEACON, GB ;

PHILLIPS, RJ .

COORDINATION CHEMISTRY REVIEWS, 1980, 33 (03) :227-250

[3] A novel lead(II) framework containing Pb-O-Pb and Pb-Cl-Pb helical chains [J].

Ding, Bin ;

Yang, En-Cui ;

Guo, Jian-Hua ;

Zhao, Xiao-Jun ;

Wang, Xiu-Guang .

INORGANIC CHEMISTRY COMMUNICATIONS, 2008, 11 (05) :509-512

[4] PHOTOCHEMICAL AND PHOTOPHYSICAL PROPERTIES OF TETRANUCLEAR AND HEXANUCLEAR CLUSTERS OF METALS WITH D10 AND S2 ELECTRONIC CONFIGURATIONS [J].

FORD, PC ;

VOGLER, A .

ACCOUNTS OF CHEMICAL RESEARCH, 1993, 26 (04) :220-226

[5] Mononuclear, oligonuclear and polynuclear metal coordination compounds with 1,2,4-triazole derivatives as ligands [J].

Haasnoot, JG .

COORDINATION CHEMISTRY REVIEWS, 2000, 200 :131-185

[6] A novel 3D porous metal-organic framework based on trinuclear cadmium clusters as a promising luminescent material exhibiting tunable emissions between UV and visible wavelengths [J].

Huang, Yong-Quan ;

Ding, Bin ;

Song, Hai-Bin ;

Zhao, Bin ;

Ren, Peng ;

Cheng, Peng ;

Wang, Hong-Gen ;

Liao, Dai-Zheng ;

Yan, Shi-Ping .

CHEMICAL COMMUNICATIONS, 2006, (47) :4906-4908

[7] 1,2,4-TRIAZOLE-3-ALANINE [J].

JONES, RG ;

AINSWORTH, C .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1955, 77 (06) :1538-1540

[8] Synthesis, structure and characterization of copper(II) and zinc(II) complexes based on 3-carboxyl-1,2,4-triazole [J].

Liu, Yuan-Yuan .

JOURNAL OF COORDINATION CHEMISTRY, 2007, 60 (22-24) :2597-2605

[9] Two novel three-dimensional lead(II) coordination polymers involving 16-membered rings:: [Pb2(Bs-glu)2(bipy)2] and [Pb2(Bs-glu)2(phen)2] [J].

Ma, LF ;

Wang, LY ;

Wang, JG ;

Wang, YF ;

Feng, X .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2006, 632 (03) :487-490

[10] Lamellar and three-dimensional hybrid compounds formed by cyclohexene- and cyclohexanedicarboxylates of Pb, La, and Cd [J].

Rao, K. Prabhakara ;

Thirumurugan, A. ;

Rao, C. N. R. .

CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (11) :3193-3201

← 1 2 3 →