Self-organization of oriented calcium carbonate/polymer composites: Effects of a matrix peptide isolated from the exoskeleton of a crayfish

被引:130
作者
Sugawara, Ayae
Nishimura, Tatsuya
Yamamoto, Yuya
Inoue, Hirotaka
Nagasawa, Hiromichi
Kato, Takashi [1 ]
机构
[1] Univ Tokyo, Sch Engn, Dept Chem & Biotechnol, Bunkyo Ku, Tokyo 1138656, Japan
[2] Univ Tokyo, Dept Appl Biol Chem, Grad Sch Agr & Life Sci, Bunkyo Ku, Tokyo 1138656, Japan
关键词
biomineralization; calcium; crystal growth; materials science; peptides;
D O I
10.1002/anie.200503800
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) Gone fishing: Unidirectionally oriented CaCO3 crystalline films have been prepared on chitin matrices in the presence of calcification-associated peptide (CAP-1), which was isolated from the exoskeleton of the red swamp crayfish. The interactions of CAP-1 with the matrix and the acidic nature of the peptide lead to a filmlike assembly of CaCO 3 nanocrystals through transformation of amorphous calcium carbonate (see picture). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:2876 / 2879
页数:4
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