Cyclisation of citronellal over heterogeneous inorganic fluorides-highly chemo- and diastereoselective catalysts for (±)-isopulegol

被引：37

作者：

Coman, Simona M. ^{[1
,2
]}

Patil, Pratap ^{[1
]}

Wuttke, Stefan ^{[1
]}

Kemnitz, Erhard ^{[1
]}

机构：

[1] Humboldt Univ, Inst Chem, D-12489 Berlin, Germany

[2] Univ Bucharest, Fac Chem, Dept Chem Technol & Catalysis, Bucharest 030016, Romania

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 04期

关键词：

CARBONYL-ENE REACTION; METAL FLUORIDES; ISOPULEGOL; ZEOLITES; IR;

D O I：

10.1039/b817572a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Based on a fluorolyticsol-gel synthesis, nanoscopic metal fluorides and partly hydroxylated metal fluorides were synthesized; varying the F : OH ratio inside these solids yielded catalysts with different combinations and variable strength Lewis and Bronsted acid sites, which demonstrated unexpected catalytic properties for the diastereoselective synthesis of (+/-)-isopulegol.

引用

页码：460 / 462

页数：3

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