Process Intensification Aspects for Steam Methane Reforming: An Overview

被引:119
作者
Bhat, Shrikant A. [1 ]
Sadhukhan, Jhuma [1 ]
机构
[1] Univ Manchester, Sch Chem Engn & Analyt Sci, Ctr Proc Integrat, Manchester M60 1QD, Lancs, England
基金
英国工程与自然科学研究理事会;
关键词
steam methane reforming; hydrogen economy; process intensification; catalyst design; multiscale modeling; ENHANCED REACTION PROCESS; PALLADIUM MEMBRANE REACTOR; CARBON-DIOXIDE SEPARATION; WATER-GAS SHIFT; CATALYTIC PARTIAL OXIDATION; DENSE CERAMIC MEMBRANES; MONTE-CARLO-SIMULATION; HYDROGEN-PRODUCTION; LITHIUM ZIRCONATE; MULTIFUNCTIONAL REACTORS;
D O I
10.1002/aic.11687
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Steam methane reforming (SMR) is the most widely used process in industry for the production of hydrogen, which is considered as the future generation energy carrier. Having been perceived as an important source of H,, there are abundant incentives for design and development of SMR processes mainly through the consideration of process intensification and multiscale modeling; two areas which are considered as the main focus of the future generation chemical engineering to meet the global energy challenges. This article presents a comprehensive overview of the process integration aspects for SMR, especially the potential for multiscale modeling in this at-ea. The intensification for SMR is achieved by coupling with adsorption and membrane separation technologies, etc., and using the concept of multifunctional reactors and catalysts to overcome the mass transfer, heat transfer, and thermodynamic limitations. In this article, the focus of existing and future research on these emerging areas has beet? drawn. (c) 2009 American Institute of Chemical Engineers AIChE J, 55: 408-422, 2009
引用
收藏
页码:408 / 422
页数:15
相关论文
共 138 条
[1]  
Abashar MEE, 2004, INT J HYDROGEN ENERG, V29, P799, DOI [10.1016/j.ijhydene.2003.09.010, 10.1016/j.jjhydene.2003.09.010]
[2]   The fluidized bed membrane reactor system: A pilot scale experimental study [J].
Adris, A. M. ;
Lim, C. J. ;
Grace, J. R. .
CHEMICAL ENGINEERING SCIENCE, 1994, 49 (24B) :5833-5843
[3]   A FLUIDIZED-BED MEMBRANE REACTOR FOR THE STEAM REFORMING OF METHANE [J].
ADRIS, AM ;
ELNASHAIE, SSEH ;
HUGHES, R .
CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 1991, 69 (05) :1061-1070
[4]   The fluidized-bed membrane reactor for steam methane reforming: Model verification and parametric study [J].
Adris, AM ;
Lim, CJ ;
Grace, JR .
CHEMICAL ENGINEERING SCIENCE, 1997, 52 (10) :1609-1622
[5]   MULTIFUNCTIONAL REACTORS FOR HETEROGENEOUS CATALYSIS [J].
AGAR, DW ;
RUPPEL, W .
CHEMIE INGENIEUR TECHNIK, 1988, 60 (10) :731-741
[6]   Multifunctional reactors: Old preconceptions and new dimensions [J].
Agar, DW .
CHEMICAL ENGINEERING SCIENCE, 1999, 54 (10) :1299-1305
[7]   KINETICS OF THE METHANE-STEAM REACTION [J].
AKERS, WW ;
CAMP, DP .
AICHE JOURNAL, 1955, 1 (04) :471-475
[8]   KINETICS OF METHANE-STEAM REACTION [J].
ALLEN, DW ;
GERHARD, ER ;
LIKINS, MR .
INDUSTRIAL & ENGINEERING CHEMISTRY PROCESS DESIGN AND DEVELOPMENT, 1975, 14 (03) :256-259
[9]  
ALUBAID AS, 1987, METH CONV S AUCKL NZ
[10]  
ANAND M, 2001, Patent No. 6303092