Novel multicomponent amorphous alloys

被引:85
作者
Cantor, B [1 ]
Kim, KB [1 ]
Warren, PJ [1 ]
机构
[1] Univ Oxford, Dept Mat, Oxford OX1 3PH, England
来源
METASTABLE, MECHANICALLY ALLOYED AND NANOCRYSTALLINE MATERIALS | 2002年 / 386-3卷
关键词
equiatomic alloy substitution; multicomponent amorphous alloy;
D O I
10.4028/www.scientific.net/MSF.386-388.27
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A wide range of novel multicomponent amorphous alloys can be manufactured by the new method of equiatomic alloy substitution for the early and late transition metal contents of Zr-based amorphous alloys. Amorphous alloys are formed by melt spinning in the alloy system A(x)-B90-xAl10 over the composition range x=20-70at% when the early transition metal A=Ti33Zr33Hf33 and the late transition metal B=Ni50Cu50. Amorphous alloys are also formed over the composition range x=50-70at%, when the early transition metal content is extended to A=Ti25Zr25Hf25Nb25, or when the late transition metal content is extended to B= Ni33Cu33Ag33. The most stable amorphous alloy of these is (Ti33Zr33Hf33)(40)(Ni50Cu50)(50)Al-10 with a crystallisation temperature of T,= 545 'C. The amorphous alloy with the largest supercooled liquid region is (Ti33Zr33Hf33)(50)(Ni-33,Cu33Ag33)(40)Al-10 with a crystallisation-glass transition temperature difference of T-x -T-g= 103 degreesC.
引用
收藏
页码:27 / 31
页数:5
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