Synthesis and reactivity of [PPh(4)][Ru(N)Me(3)(SSiMe(3))], a ruthenium(VI) trimethylsilanethiolate complex

被引：31

作者：

Liang, HC

Shapley, PA

机构：

[1] University of Illinois, School of Chemical Sciences, Urbana

来源：

ORGANOMETALLICS | 1996年 / 15卷 / 05期

关键词：

D O I：

10.1021/om950696i

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The anionic organoruthenium complex [PPh(4)][Ru(N)Me(3)Br] reacts with NaSSiMe(3) to give the trimethylsilanethiolate complex [PPh(4)][Ru(N)Me(3)SSiMe(3)], 1. Reactions of 1 with CsF or with PPh(4)Cl in nitromethane or acetonitrile produce [PPh(4)][Ru(N)Me(3)(SH)], 2. The molecular structure of 2 was determined by X-4ay diffraction. Complex 1 reacts with [Os(N)(CH(2)SiMe(3))(2)-(mu-Cl)](2) to form a heterobimetallic complex, [PPh(4)][Me(3)-(N)Ru(mu-S)Os(N)(CH(2)SiMe(3))(2)(NCCH3)], 3.

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页码：1331 / 1333

页数：3

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