Native silica nanoparticle catalyzed anti-Markovnikov addition of thiols to inactivated alkenes and alkynes: a new route to linear and vinyl thioethers

被引：53

作者：

Banerjee, Subhash ^{[1
]}

Das, Jayanta ^{[1
,2
]}

Santra, Swadeshmukul ^{[1
,2
,3
]}

机构：

[1] Univ Cent Florida, NanoSci Technol Ctr, Orlando, FL 32826 USA

[2] Univ Cent Florida, Dept Chem, Orlando, FL 32826 USA

[3] Univ Cent Florida, Biomol Sci Ctr, Coll Med, Orlando, FL 32826 USA

来源：

TETRAHEDRON LETTERS | 2009年 / 50卷 / 01期

基金：

美国国家科学基金会;

关键词：

Silicananoparticle; Catalysis; Anti-Markovnikov addition; Solvent-free reaction condition; Linear and vinyl thioethers; Reuse of catalyst; PALLADIUM; SULFIDES; OLEFINS;

D O I：

10.1016/j.tetlet.2008.10.110

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new route for the synthesis of linear and vinyl thioethers has been demonstrated using bare silica nanoparticle as catalyst at room temperature under solvent-free conditions. The catalyst can be reused up to six times without loss of catalytic activity. (C) 2008 Elsevier Ltd. All rights reserved.

引用

收藏

页码：124 / 127

页数：4

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