photo-isomerization;
photoinduced transition;
high pressure studies;
D O I:
10.1016/j.tca.2005.11.012
中图分类号:
O414.1 [热力学];
学科分类号:
摘要:
High pressure investigations have been carried out on the photo-stimulated phase transition exhibited by a guest-host system, where the host is a non-photoactive liquid crystal. As guest molecules we chose successive homologues of a dimeric photoactive azobenzene liquid crystalline molecule to understand the influence of the length and parity of the alkylene spacer on such a transition. Our studies show that application of pressure as well as the parity of the spacer has a drastic influence both on the static and dynamic characters of the photo-stimulated phase transition. (C) 2005 Elsevier B.V. All rights reserved.