Encapsulation of hydrogen in cadmium-exchanged zeolite rho; Temperature-programmed diffusion studies

被引：5

作者：

Krishnan, VV

Suib, SL

Corbin, DR

Schwarz, S

Jones, GA

机构：

[1] UNIV CONNECTICUT,DEPT CHEM ENGN,STORRS,CT 06269

[2] UNIV CONNECTICUT,DEPT CHEM,STORRS,CT 06269

[3] UNIV CONNECTICUT,INST MAT SCI,STORRS,CT 06269

[4] DUPONT CO INC,CENT RES & DEV,EXPTL STN,WILMINGTON,DE 19880

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 03期

关键词：

D O I：

10.1039/cc9960000395

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cadmium-exchanged zeolite rho encapsulates 161 mu mol g(-1) of hydrogen at 100 degrees C and 620 mu mol g(-1) at 200 degrees C, (in 2 h and at 1 atm), the highest ever observed for any zeolite at 1 atm; hydrogen-exchanged zeolite rho, however, shows negligible uptake of hydrogen, providing evidence that the cadmium ion is directly responsible for hydrogen encapsulation.

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收藏

页码：395 / 396

页数：2

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