Gold(III)-induced oxidation of glycine

被引：57

作者：

Zou, J ^{[1
]}

Guo, ZJ ^{[1
]}

Parkinson, JA ^{[1
]}

Chen, Y ^{[1
]}

Sadler, PJ ^{[1
]}

机构：

[1] Univ Edinburgh, Dept Chem, Edinburgh EH9 3JJ, Midlothian, Scotland

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 15期

关键词：

D O I：

10.1039/a902646k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

NMR investigations of isotopically-labelled glycine show that Au-III induces deamination and subsequent decarboxylation of the amino acid with formation of glyoxylic acid, NH4+, formic acid, CO2 and metallic gold.

引用

页码：1359 / 1360

页数：2

共 34 条

[1] INTRINSIC STERIC DEUTERIUM-ISOTOPE EFFECTS ON PROTON AND C-13 CHEMICAL-SHIFTS [J].

ANET, FAL ;

DEKMEZIAN, AH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (18) :5449-5451

[2] PHOTOCHEMISTRY OF COORDINATION COMPOUNDS .14. ELECTRON TRANSFER AND D-D EXCITATION IN COBALT(3)-AMINO ACID COMPLEXES [J].

BALZANI, V ;

CARASSIT.V ;

MOGGI, L ;

SABBATIN.N .

INORGANIC CHEMISTRY, 1965, 4 (09) :1247-&

[3]

BernersPrice SJ, 1996, COORDIN CHEM REV, V151, P1

[4]

Best S.L., 1996, GOLD BULL, V29, P87, DOI [10.1007/BF02004707, DOI 10.1007/BF03214741]

[5]

BEST SL, 1996, THESIS U LONDON

[6] STEREOSPECIFIC OXIDATION OF METHIONINE TO METHIONINE SULFOXIDE BY TETRACHLOROAURIC(III) ACID [J].

BORDIGNON, E ;

CATTALINI, L ;

NATILE, G ;

SCATTURIN, A .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1973, (22) :878-879

[7] A LIFE TABLE FOR POWAN, COREGONUS-LAVARETUS (L) IN LOCH LOMOND, SCOTLAND - A BASIS FOR CONSERVATION STRATEGY [J].

BROWN, EAR ;

FINNIGAN, N ;

SCOTT, DBC .

AQUATIC CONSERVATION-MARINE AND FRESHWATER ECOSYSTEMS, 1991, 1 (02) :183-187

[8]

Calamai P, 1998, ANTI-CANCER DRUG DES, V13, P67

[9] HOS3(CO)10CH3 - NMR EVIDENCE FOR A C..H..OS INTERACTION [J].

CALVERT, RB ;

SHAPLEY, JR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (24) :7726-7727

[10] Interconversion between S- and N-bound L-methionine adducts of pt(dien)2+ (dien = diethylenetriamine) via dien ring-opened intermediates [J].

Chen, Y ;

Guo, ZJ ;

Murdoch, PD ;

Zang, EL ;

Sadler, PJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (09) :1503-1508

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