Three-dimensional Hemidirected Mixed-ligand Lead(II) Coordination Polymer, [Pb2(bpa)2(SCN)3(NO3)]n (bpa=1,2-di(4-pyridyl)ethane)

被引：9

作者：

Abedini, Jafar ^{[2
]}

Morsali, Ali ^{[1
]}

Zeller, Matthias ^{[3
]}

机构：

[1] Tarbiat Modares Univ, Fac Sci, Dept Chem, Tehran, Iran

[2] Payame Noor Univ, Dept Sci, Abhar, Zanjan, Iran

[3] Youngstown State Univ, Dept Chem, Youngstown, OH 44555 USA

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2008年 / 634卷 / 14期

关键词：

Lead; 1,2-di(4-pyridyl)ethane; Coordination polymer;

D O I：

10.1002/zaac.200800333

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new 3D hemidirected mixed-ligand lead(II) coordination polymer with the ligand 1,24(4-pyridyl)ethane bpa) and the two metal coordinated anions nitrate and thiocyanate, [Pb-2(bpa)(2)(SCN)(3)(NO3)](n) (1), has been synthesized and characterized by CHN elemental analysis, IR-, H-1- and C-13 NMR spectroscopy. The single crystal X-ray data of compound 1 show that the complex is a three-dimensional coordination polymer with two different Pb atoms with stereoactive electron lone pairs and six- and five-coordinate hemidirected geometries, respectively.

引用

页码：2659 / 2662

页数：4

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