Stereochemical control in the silyl triflate-mediated Claisen rearrangement of allylic esters

被引：30

作者：

Kobayashi, M ^{[1
]}

Masumoto, K ^{[1
]}

Nakai, E ^{[1
]}

Nakai, T ^{[1
]}

机构：

[1] TOKYO INST TECHNOL,DEPT CHEM TECHNOL,MEGURO KU,TOKYO 152,JAPAN

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 17期

关键词：

D O I：

10.1016/0040-4039(96)00485-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The titled Claisen modification is shown to proceed with a remarkably high level of diastereoselection and asymmetric transmission by virtue of the proper choice of the combination of the silyl triflate and the tertiary amine used. (C) 1996 Published by Elsevier Science Ltd

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页码：3005 / 3008

页数：4

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