Stereospecific synthesis of chiral N-(ethynyl)allylglycines and their use in highly stereoselective intramolecular Pauson-Khand reactions

被引：87

作者：

Witulski, B ^{[1
]}

Gossmann, M ^{[1
]}

机构：

[1] Univ Kaiserslautern, Fachbereich Chem, D-67663 Kaiserslautern, Germany

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 18期

关键词：

D O I：

10.1039/a905898b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first synthesis of an enantiopure N-ethynylated allylglycine and its application in the intramolecular Pauson-Khand reaction, which leads to a novel highly functionalised proline derivative with complete control of stereoselectivity, is reported.

引用

页码：1879 / 1880

页数：2

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