Cobalt-mediated radical polymerization of vinyl acetate in miniemulsion:: Very fast formation of stable poly(vinyl acetate) latexes at low temperature

被引：47

作者：

Detrembleur, C

Debuigne, A

Bryaskova, R

Charleux, B

Jérôme, R

机构：

[1] Univ Liege, CERM, B-4000 Liege, Belgium

[2] Univ Paris 06, Lab Chim Polymeres, CNRS, UMR 7610, F-75252 Paris 05, France

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2006年 / 27卷 / 01期

关键词：

Co(acac)(2); latex; living polymerization; poly(vinyl acetate); radical polymerization;

D O I：

10.1002/MARC.200500645

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Poly(vinyl acetate) macroinitiators end-capped by a Co(acac)(2) complex (PVAc-Co(acac)(2)), prepared in bulk by cobalt-mediated radical polymerization (CMRP), are used for the controlled radical polymerization of vinyl acetate in miniemulsion to give high-molecular-weight polymers and high monomer conversion. Stable poly(vinyl acetate) latexes with solid contents ranging from 25 to 30 wt.-% are prepared within unusually short reaction times (similar to 1 h) at low temperatures (0-30 degrees C).

引用

页码：37 / 41

页数：5

共 19 条

[1] Maximizing polymer livingness in nitroxide-mediated miniemulsion polymerizations [J].