Two-dimensional rare earth coordination polymers involving different coordination modes of thiodiglycolic acid

被引：29

作者：

Zhang, YZ ^{[1
]}

Li, JR ^{[1
]}

Gao, S ^{[1
]}

Kou, HZ ^{[1
]}

Sun, HL ^{[1
]}

Wang, ZM ^{[1
]}

机构：

[1] Peking Univ, Coll Chem & Mol Engn, PKU HKU Joint Lab Rare Earth Mat & Bioinorgan Che, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2002年 / 5卷 / 01期

基金：

中国国家自然科学基金;

关键词：

coordination polymer; coordination modes; double-layered structure; lanthanide;

D O I：

10.1016/S1387-7003(01)00330-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two coordination polymers [La-2(tdga)(3)(H2O)(2)](n) (1) and {[Pr-2 (tdga)(3) (H2O)(2)] (.) H2O}(n) (2) were obtained by the reaction between Ln(OH)(3) (Ln = La, Pr) and thiodiglycolic acid (H(2)tdga = H2S(CH2CO2)(2)). which have a novel double-layered and a single-layered structure, respectively. In the complexes, new coordination modes of the ligand were observed. (C) 2002 Elsevier Science B.V. All rights reserved.

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页码：28 / 31

页数：4

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