A direct approach to selective sulfonation of triarylphosphines

被引：32

作者：

Gulyás, H

Szollosy, A

Hanson, BE

Bakos, J

机构：

[1] Univ Veszprem, Dept Organ Chem, H-8201 Veszprem, Hungary

[2] Hungarian Acad Sci, Res Grp Petrochem, H-8201 Veszprem, Hungary

[3] Tech Univ Budapest, Dept Gen & Analyt Chem, H-1521 Budapest, Hungary

[4] Virginia Polytech Inst & State Univ, Dept Chem, Blacksburg, VA 24061 USA

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 14期

关键词：

sulfonation; phosphines water-soluble;

D O I：

10.1016/S0040-4039(02)00319-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A practical and convenient synthesis of mono-, di- and a trisulfonated phosphines from triphenylphosphine analogs, (2,4-dimethylphenyl)(3-n)-(phenyl)(n)-phosphine and (4-methoxyphenyl)(3-n)-(phenyl)(n)-phosphine (n = 0-2), is described, respectively. This represents an easy way to prepare water-soluble phosphines with complete selectivity, and with essentially no phosphine oxide formation. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：2543 / 2546

页数：4

共 28 条

[1] THE RELATIVE AFFINITIES OF CO-ORDINATING ATOMS FOR SILVER ION .2. NITROGEN, PHOSPHORUS, AND ARSENIC
AHRLAND, S
CHATT, J
DAVIES, NR
WILLIAMS, AA
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1958, (JAN): : 276 - 288
[2] [Anonymous], 1995, ANGEW CHEM, V107, P893
[3] COMMENTS ON THE SYNTHESIS OF TRISULFONATED TRIPHENYLPHOSPHINE - REACTION MONITORING BY NMR-SPECTROSCOPY
BARTIK, T
BARTIK, B
HANSON, BE
GLASS, T
BEBOUT, W
[J]. INORGANIC CHEMISTRY, 1992, 31 (12) : 2667 - 2670
[4] ZWITTERIONIC METAL-COMPLEXES OF THE NEW TRIPHOSPHINE NAO3S(C6H4)CH2C(CH(2)PPH(2))(3) IN LIQUID BIPHASIC CATALYSIS - AN ALTERNATIVE TO TEFLON PONYTAILS FOR FACILE CATALYST SEPARATION WITHOUT WATER
BIANCHINI, C
FREDIANI, P
SERNAU, V
[J]. ORGANOMETALLICS, 1995, 14 (12) : 5458 - 5459
[5] Bulk and fine chemicals via aqueous biphasic catalysis
Cornils, B
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1999, 143 (1-3) : 1 - 10
[6] Industrial aspects of aqueous catalysis
Cornils, B
Herrmann, WA
Eckl, RW
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1997, 116 (1-2) : 27 - 33
[7] INTRODUCING TPPTS AND RELATED LIGANDS FOR INDUSTRIAL BIPHASIC PROCESSES
CORNILS, B
KUNTZ, EG
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 502 (1-2) : 177 - 186
[8] ANODIC BEHAVIOR OF CROWDED TRIARYLPHOSPHINES - ESR STUDY OF TRIARYLPHOSPHONIUMYL RADICALS, AR3P.+
CULCASI, M
BERCHADSKY, Y
GRONCHI, G
TORDO, P
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (11) : 3537 - 3542
[9] SULFONATED PHOSPHINES
Ding, H
Bunn, BB
Hanson, BE
Eckl, RW
Kohlpaintner, CW
Herrmann, WA
[J]. INORGANIC SYNTHESES, VOL 32, 1998, 32 : 29 - 36
[10] PREPARATION OF A SURFACE-ACTIVE CHIRAL DIPHOSPHANE AND ITS USE IN THE HYDROGENATION OF PROCHIRAL OLEFINS
DING, H
HANSON, BE
BAKOS, J
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (15): : 1645 - 1647

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