Toward a 'reagent-free' synthesis - Tandem enzymatic and electrochemical methods for increased effective mass yield (EMY)

被引:80
作者
Hudlicky, T [1 ]
Frey, DA [1 ]
Koroniak, L [1 ]
Claeboe, CD [1 ]
Brammer, LE [1 ]
机构
[1] Univ Florida, Dept Chem, Gainesville, FL 32611 USA
关键词
D O I
10.1039/a901397k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Several synthetic pathways to cyclohex-5-ene-1R,2S,3R,4R-tetrol (conduritol C) and cyclohex-5-ene-1S,2R,3R,4R- tetrol (conduritol F) are compared; each is analyzed for effectiveness of waste minimization. The latest synthesis, reported in this manuscript, combines enzymatic transformations with electrochemical methods. The concept of "effective mass yield" (EMY) is defined and illustrated.
引用
收藏
页码:57 / 59
页数:3
相关论文
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